苹果原花青素与酞菁氧钛络合的手性识别
Chiral recognition of apple procyanidins by complexation with oxotitanium phthalocyanine.
作者信息
Muranaka Atsuya, Yoshida Kengo, Shoji Toshihiko, Moriichi Nina, Masumoto Saeko, Kanda Tomomasa, Ohtake Yasuyuki, Kobayashi Nagao
机构信息
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
出版信息
Org Lett. 2006 Jun 8;8(12):2447-50. doi: 10.1021/ol060312s.
PMID:16737285
Abstract
A series of supramolecular complexes formed between oxotitanium(IV) phthalocyanine and apple procyanidins have exhibited characteristic bisignate CD signals in the Q region (ca. 700 nm). The helicity of the oligomeric procyanidins is proposed to be left-handed on the basis of the CD analyses. [structure: see text]
摘要
一系列在酞菁氧钛（IV）和苹果原花青素之间形成的超分子配合物在Q区域（约700纳米）呈现出特征性的双信号圆二色（CD）信号。基于圆二色分析，推测低聚原花青素的螺旋性为左旋。[结构：见正文]
Zotero 插件