首个结构特征明确的亚硝酰基硫醇血红素模型配合物。
The first structurally characterized nitrosyl heme thiolate model complex.
作者信息
Xu Nan, Powell Douglas R, Cheng Lin, Richter-Addo George B
机构信息
Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, Oklahoma, USA.
出版信息
Chem Commun (Camb). 2006 May 21(19):2030-2. doi: 10.1039/b602611g. Epub 2006 Apr 11.
DOI:10.1039/b602611g
PMID:16767265
Abstract
The NO ligand in the formally {FeNO}6 compound [Fe(oep)(NO)(thiolate)] is bent, and does not impart a significant structural trans effect to the Fe-S bond.
摘要
在形式上为{FeNO}6化合物[Fe(oep)(NO)(硫醇盐)]中的NO配体是弯曲的，并且不会对Fe-S键产生显著的结构反位效应。
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