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[BC(x)N薄膜的紫外透射光谱]

[Ultraviolet transmission spectra of BC(x)N thin films].

作者信息

Wang Yu-xin, Feng Ke-cheng, Li Ying-ai, Li Wei-qing, Liu Li-hua, Zhao Chun-hong, Zhao Yong-nian

机构信息

College of Science, Changchun University of Science and Technology, Changchun 130022, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2006 Jan;26(1):102-5.

Abstract

BCN, BC2N and BC3N thin films with transmission increasing properties in the ultraviolet region were deposited by RF magnetron sputtering with different sputtering power (80-130 W). Fourier transform infrared absorption and X-ray photoelectron spectroscopy results suggested that the films were atomnic-level hybrids composed of B, 'C and N atoms. The compositions and transmission increasing properties of samples in the ultraviolet region were strongly influenced by sputtering power, which determined the transmission increasing properties in the ultraviolet region by changing compositions. And the lower the atomic number of C in the thin films, the better the transmission increasing properties in the ultraviolet region. The BCN thin films deposited at the sputtering power of 110 W possessed the lowest atonic number of C and the best transmission increasing properties in the ultraviolet region. And the increase in average transmissivity from 200 to 350 nm was about 40% compared with glass.

摘要

采用射频磁控溅射法,在不同溅射功率(80 - 130 W)下制备了在紫外区域具有透过率增加特性的BCN、BC₂N和BC₃N薄膜。傅里叶变换红外吸收和X射线光电子能谱结果表明,这些薄膜是由B、C和N原子组成的原子级杂化物。样品在紫外区域的组成和透过率增加特性受溅射功率的强烈影响,溅射功率通过改变组成来决定紫外区域的透过率增加特性。并且薄膜中C的原子序数越低,在紫外区域的透过率增加特性越好。在110 W溅射功率下沉积的BCN薄膜具有最低的C原子序数和在紫外区域最佳的透过率增加特性。与玻璃相比,在200至350 nm范围内平均透过率的增加约为40%。

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