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采用CPMG序列的调制梯度自旋回波对多孔介质中扩散进行光谱表征。

Spectral characterization of diffusion in porous media by the modulated gradient spin echo with CPMG sequence.

作者信息

Stepisnik Janez, Lasic Samo, Mohoric Ales, Sersa Igor, Sepe Ana

机构信息

University of Ljubljana, Faculty of Mathematics and Physics, Physics Department, Jadranska 19, 1000 Ljubljana, Slovenia.

出版信息

J Magn Reson. 2006 Oct;182(2):195-9. doi: 10.1016/j.jmr.2006.06.023. Epub 2006 Jul 17.

Abstract

Carr-Purcell-Meiboom-Gill train of radiofrequency pulses applied to spins in the constant magnetic field gradient is an efficient variant of the modulated magnetic field gradient spin echo method, which provides information about molecular diffusion in the frequency-domain instead in the time-domain as with the two-pulse gradient spin echo. The frequency range of novel technique is broad enough to sample the power spectrum of displacement fluctuation in water-saturated pulverized silica (SiO(2)) and provides comprehensive information about the molecular restricted motion as well as about the structure of medium.

摘要

应用于恒定磁场梯度中自旋的 Carr-Purcell-Meiboom-Gill 射频脉冲序列是调制磁场梯度自旋回波方法的一种有效变体,它在频域而非时域提供有关分子扩散的信息,这与时域的双脉冲梯度自旋回波不同。新技术的频率范围足够宽,能够对水饱和的粉碎二氧化硅(SiO₂)中位移涨落的功率谱进行采样,并提供有关分子受限运动以及介质结构的全面信息。

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