Stepisnik Janez, Lasic Samo, Mohoric Ales, Sersa Igor, Sepe Ana
University of Ljubljana, FMF Physics Department, J. Stefan Institute, 1000 Ljubljana, Slovenia.
Magn Reson Imaging. 2007 May;25(4):517-20. doi: 10.1016/j.mri.2007.01.001. Epub 2007 Mar 12.
Carr-Purcell-Meiboom-Gill (CPMG) train of radiofrequency pulses applied to spins in the constant magnetic field gradient is an efficient variant of the modulated magnetic field gradient spin echo method, which provides information about molecular diffusion in the frequency domain instead of in the time domain as with the two-pulse gradient spin echo. The frequency range of this novel technique is broad enough to sample the power spectrum of displacement fluctuation in water-saturated pulverized silica (SiO2) and provides comprehensive information about the molecular restricted motion as well as about the structure of the medium.
施加于恒定磁场梯度中自旋的 Carr-Purcell-Meiboom-Gill(CPMG)射频脉冲序列是调制磁场梯度自旋回波方法的一种有效变体,它在频域而非时域中提供有关分子扩散的信息,这与时域中的双脉冲梯度自旋回波不同。这种新技术的频率范围足够宽,能够对水饱和的粉状二氧化硅(SiO₂)中位移涨落的功率谱进行采样,并提供有关分子受限运动以及介质结构的全面信息。