Demirplak Mustafa, Rice Stuart A
Department of Chemistry and The James Franck Institute, The University of Chicago, Chicago, Illinois 60637, USA.
J Phys Chem B. 2005 Apr 14;109(14):6838-44. doi: 10.1021/jp040647w.
We report the results of studies of various aspects of the counter diabatic field paradigm, a recipe that generates adiabatic population transfer between levels by assisting a given field so that the total field generates the population transfer that the adiabatic approximation suggests for the given field. The sensitivity of this recipe to the pulse parameters and to Gaussian stochastic phase fluctuations between the fields has been investigated. Ladder-climbing population transfer between the vibrational levels of a nonrotating Morse oscillator is examined, and a numerical demonstration of the efficiency of the scheme is given.
我们报告了对反绝热场范式各个方面的研究结果，该范式是一种通过辅助给定场来在能级之间产生绝热布居转移的方法，使得总场产生绝热近似针对给定场所表明的布居转移。已经研究了该方法对脉冲参数以及场之间高斯随机相位涨落的敏感性。研究了非旋转莫尔斯振子振动能级之间的阶梯爬升布居转移，并给出了该方案效率的数值演示。
