负载于含类离子液体部分的整体聚合物上的钯(0)。在近临界乙醇中进行Heck反应的连续流动催化。
Pd(0) supported onto monolithic polymers containing IL-like moieties. Continuous flow catalysis for the Heck reaction in near-critical EtOH.
作者信息
Karbass Naima, Sans Victor, Garcia-Verdugo Eduardo, Burguete M Isabel, Luis Santiago V
机构信息
Dept. of Inorganic and Organic Chemistry, A U for Advanced Organic Materials, University Jaume I/CSIC, E-12071, Castellón, Spain.
出版信息
Chem Commun (Camb). 2006 Aug 7(29):3095-7. doi: 10.1039/b603224a. Epub 2006 Jun 14.
DOI:10.1039/b603224a
PMID:16855697
Abstract
Long-term stable Pd(0) catalysts can be easily supported onto polymeric monoliths containing methyl-imidazole moieties and the corresponding reactors based on these materials can be applied for the continuous Heck reaction in near-critical EtOH.
摘要
长期稳定的钯（0）催化剂可以很容易地负载到含有甲基咪唑基团的聚合物整料上，基于这些材料的相应反应器可用于在近临界乙醇中进行连续的Heck反应。
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