Arpaç E, Sayilkan F, Asiltürk M, Tatar P, Kiraz Nadir, Sayilkan H
Akdeniz University, Faculty of Arts and Science, Department of Chemistry, 07100 Antalya, Turkey.
J Hazard Mater. 2007 Feb 9;140(1-2):69-74. doi: 10.1016/j.jhazmat.2006.06.057. Epub 2006 Jun 21.
Sn-doped and undoped nano-TiO(2) particles have been synthesized by hydrotermal process without solvent at 200 degrees C in 1h. Nanostructure-TiO(2) based thin films have been prepared on glass substrate by spin-coating technique. The structure, surface morphology and optical properties of the thin films and the particles have been investigated by element analysis and XRD, SEM, BET and UV-vis-NIR techniques. The photocatalytic performance of the films were tested for degradation of Malachite Green dye in solution under UV and vis-lights. The results showed that (a) hydrothermally synthesized nano-TiO(2) particles are fully anatase crystalline form and are easily dispersed in water, (b) the coated surfaces have nearly super-hydrophilic properties and, (c) the doping of transition metal ion efficiently improved the photocatalytic performance of the TiO(2) thin film.
通过水热法在200℃无溶剂条件下1小时合成了掺锡和未掺锡的纳米TiO₂颗粒。采用旋涂技术在玻璃基板上制备了基于纳米结构TiO₂的薄膜。通过元素分析、XRD、SEM、BET和UV-vis-NIR技术对薄膜和颗粒的结构、表面形貌及光学性能进行了研究。测试了薄膜在紫外光和可见光下对溶液中孔雀石绿染料的光催化降解性能。结果表明:(a)水热合成的纳米TiO₂颗粒为完全锐钛矿晶型,且易分散于水中;(b)涂层表面具有近乎超亲水的性质;(c)过渡金属离子掺杂有效提高了TiO₂薄膜的光催化性能。