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玻璃基底上掺锡(IV)二氧化钛薄膜的光催化抗菌性能

Photocatalytic antibacterial performance of Sn(4+)-doped TiO(2) thin films on glass substrate.

作者信息

Sayilkan Funda, Asiltürk Meltem, Kiraz Nadir, Burunkaya Esin, Arpaç Ertuğrul, Sayilkan Hikmet

机构信息

Prof.Dr.Hikmet Sayilkan Research & Development Laboratory for Advanced Materials, Inönü University, 44280 Malatya, Turkey.

出版信息

J Hazard Mater. 2009 Mar 15;162(2-3):1309-16. doi: 10.1016/j.jhazmat.2008.06.043. Epub 2008 Jun 20.

Abstract

Pure anatase, nanosized and Sn(4+) ion doped titanium dioxide (TiO(2)) particulates (TiO(2)-Sn(4+)) were synthesized by hydrothermal process. TiO(2)-Sn(4+) was used to coat glass surfaces to investigate the photocatalytic antibacterial effect of Sn(4+) doping to TiO(2) against gram negative Escherichia coli (E. coli) and gram positive Staphylococcus aureus (S. aureus). Relationship between solid ratio of TiO(2)-Sn(4+) in coatings and antibacterial activity was reported. The particulates and the films were characterized using particle size analyzer, zeta potential analyzer, Brunauer-Emmett-Teller (BET), X-ray diffractometer (XRD), SEM, AAS and UV/VIS/NIR techniques. The results showed that TiO(2)-Sn(4+) is fully anatase crystalline form and easily dispersed in water. Increasing the solid ratio of TiO(2)-Sn(4+) from 10 to 50% in the coating solution increased antibacterial effect.

摘要

通过水热法合成了纯锐钛矿型、纳米尺寸且掺有Sn(4+)离子的二氧化钛(TiO₂)颗粒(TiO₂ - Sn(4+))。使用TiO₂ - Sn(4+)对玻璃表面进行涂层处理,以研究Sn(4+)掺杂到TiO₂中对革兰氏阴性大肠杆菌(E. coli)和革兰氏阳性金黄色葡萄球菌(S. aureus)的光催化抗菌效果。报道了涂层中TiO₂ - Sn(4+)的固含量与抗菌活性之间的关系。使用粒度分析仪、zeta电位分析仪、布鲁诺尔-埃米特-泰勒(BET)法、X射线衍射仪(XRD)、扫描电子显微镜(SEM)、原子吸收光谱仪(AAS)以及紫外/可见/近红外(UV/VIS/NIR)技术对颗粒和薄膜进行了表征。结果表明,TiO₂ - Sn(4+)为完全锐钛矿晶型,且易于分散在水中。将涂层溶液中TiO₂ - Sn(4+)的固含量从10%提高到50%可增强抗菌效果。

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