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采用电感耦合等离子体发射光谱法(ICP-AES)测定科卡巴斯溪(土耳其恰纳卡莱省比加市)废水中重金属污染与环境理化参数的关系。

Determination of heavy metal pollution with environmental physicochemical parameters in waste water of Kocabas Stream (Biga, Canakkale, Turkey) by ICP-AES.

作者信息

Yayintas Ozlem Tonguc, Yilmaz Selahattin, Turkoglu Muhammet, Dilgin Yusuf

机构信息

Biga Vocational College, Technical Programme, University of Canakkale Onsekiz Mart, 17200, Biga - Canakkale, Turkey.

出版信息

Environ Monit Assess. 2007 Apr;127(1-3):389-97. doi: 10.1007/s10661-006-9288-4. Epub 2006 Aug 5.

DOI:10.1007/s10661-006-9288-4
PMID:16897498
Abstract

Waste water pollution of industrial areas can answer for the serious consequences of one of the most important environmental threats to the future. In this study, inductively coupled plasma-atomic emission spectrometry method (ICP-AES) is proposed to determine heavy metals (Pb, Cu, Cd, Cr, Zn, Al, Fe, Ni, Co, Mn) and major elements (Ca, Mg) in waste water of Kocabas Stream. The concentration of metals in the waste water samples taken from 9 different stations (St.) in Biga-Kocabas Stream in November 2004 (autumn period) were determined after simple pretreatment of samples by the proposed ICP-AES method. An analysis of a given sample is completed in about 15 min for ICP-AES the method. The results of heavy metals concentrations in waste water were found between 0.00001-77.69610 mg l(-1) by the ICP-AES technique. The concentrations of Pb, Cd, Cu, Zn, Cr, Al, Fe, Mn, Ni, Co, Mg and Ca 0.00001 (St.3,6,7) - 0.0087 mg l(-1) (St.9), 0.00001 (St.4-7) - 0.0020 mg l(-1) (St.8), 0.00001 (St.1,3-7,9) - 0.0041 mg l(-1) (St.2), 0.0620 (St.2) - 0.2080 mg l(-1) (St.3), 0.0082 (St.6) - 0.2290 mg l(-1) (St.8), 0.3580 (St.2) - 1.7400 mg l(-1) (St.3), 0.2240 (St.1) - 0.6790 mg l(-1) (St.3), 0.0080 (St.1) - 1.5840 mg l(-1) (St.3), 0.0170 (St.3) - 0.0640 mg l(-1) (St.2), 0.0010 (St.1,4,5,8) - 0.0080 mg l(-1) (St.3), 5.0640 (St.9) - 5.2140 mg l(-1) (St.1) and 43.3600 (St.2) - 77.6961 mg l(-1) (St.9), respectively. Also we measured environmental physicochemical parameters such as temperature, salinity, specific conductivity, total dissolved solid (TDS), pH, oxidation and reduction potential (ORP), and dissolved oxygen (DO) in the waste water at sampling stations.

摘要

工业区的废水污染可能是未来最重要的环境威胁之一的严重后果的原因。在本研究中,提出了电感耦合等离子体原子发射光谱法(ICP - AES)来测定科贾巴斯溪废水中的重金属(铅、铜、镉、铬、锌、铝、铁、镍、钴、锰)和主要元素(钙、镁)。2004年11月(秋季)从比加 - 科贾巴斯溪9个不同站点采集的废水样本,经简单预处理后,采用所提出的ICP - AES方法测定其中金属的浓度。对于ICP - AES方法,分析一个给定样本大约需要15分钟。通过ICP - AES技术,发现废水中重金属浓度在0.00001 - 77.69610 mg l⁻¹之间。铅、镉、铜、锌、铬、铝、铁、锰、镍、钴、镁和钙的浓度分别为0.00001(站点3、6、7) - 0.0087 mg l⁻¹(站点9)、0.00001(站点4 - 7) - 0.0020 mg l⁻¹(站点8)、0.00001(站点1、3 - 7、9) - 0.0041 mg l⁻¹(站点2)、0.0620(站点2) - 0.2080 mg l⁻¹(站点3)、0.0082(站点6) - 0.2290 mg l⁻¹(站点8)、0.3580(站点2) - 1.7400 mg l⁻¹(站点3)、0.2240(站点1) - 0.6790 mg l⁻¹(站点3)、0.0080(站点1) - 1.5840 mg l⁻¹(站点3)、0.0170(站点3) - 0.0640 mg l⁻¹(站点2)、0.0010(站点1、4、5、8) - 0.008 mg l⁻¹(站点3)、5.0640(站点9) - 5.2140 mg l⁻¹(站点1)和43.3600(站点2) - 77.6961 mg l⁻¹(站点9)。此外,我们还测量了采样站点废水中的环境物理化学参数,如温度、盐度、电导率、总溶解固体(TDS)、pH值、氧化还原电位(ORP)和溶解氧(DO)。

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