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槲小蠹聚集信息素（1S,4R）-对-薄荷-2-烯-1-醇（quercivorol）的绝对构型测定，该信息素由槲小蠹（鞘翅目：长小蠹科）产生 。

Determination of the absolute configuration of quercivorol, (1S,4R)-p-menth-2-en-1-ol, an aggregation pheromone of the ambrosia beetle Platypus quercivorus (Coleoptera: Platypodidae).

作者信息

Kashiwagi Takehiro, Nakashima Tadakazu, Tebayashi Shin-ich, Kim Chul-Sa

机构信息

Department of Biomechanical System, Faculty of Agriculture, Ehime University, Japan.

出版信息

Biosci Biotechnol Biochem. 2006 Oct;70(10):2544-6. doi: 10.1271/bbb.60211. Epub 2006 Oct 7.

DOI:10.1271/bbb.60211
PMID:17031065
Abstract

A pair of enantiomers of trans-p-menth-2-en-1-ol, an aggregation pheromone of Platypus quercivorus, was synthesized from (S)- and (R)-limonene. The retention time of the aggregation pheromone from the insect coincided with that of (1S,4R)-p-menth-2-en-1-ol synthesized from (S)-limonene from GC analyses with a chiral column, enabling the absolute configuration of the aggregation pheromone to be determined as (1S,4R).

摘要

从（S）-和（R）-柠檬烯合成了日本齿小蠹聚集信息素反式-对-薄荷-2-烯-1-醇的一对对映体。通过使用手性柱的气相色谱分析，昆虫聚集信息素的保留时间与由（S）-柠檬烯合成的（1S，4R）-对-薄荷-2-烯-1-醇的保留时间一致，从而能够确定聚集信息素的绝对构型为（1S，4R）。

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