Manciu Marian, Ruckenstein Eli
Physics Department, University of Texas at El Paso, USA.
J Colloid Interface Sci. 2006 Dec 15;304(2):541-4. doi: 10.1016/j.jcis.2006.09.034. Epub 2006 Sep 20.
In a recent review of this topic [B.C. Garett, Science 303 (2004) 1146] the emphasis was on some recent experiments, in which it was found that some anions accumulate at the air/water interface and not in the bulk, as usually happens to the cations, and on some simulations which explained those positive surface adsorption excesses. Because a large number of these experiments could be explained on the basis of some simple physical models proposed by the authors for the interaction between the ions and the air/water interface [M. Manciu, E. Ruckenstein, Adv. Colloid Interface Sci. 105 (2003) 63; Adv. Colloid Interface Sci. 112 (2004) 109; Langmuir 21 (2005) 11312], those models are reviewed in the present note, the goal being to draw attention to them.
在最近一篇关于该主题的综述文章[B.C. 加勒特，《科学》303 (2004) 1146]中，重点关注了一些近期实验，实验发现一些阴离子聚集在空气/水界面而非本体相中，这与阳离子通常的情况不同，同时还关注了一些解释这些正表面吸附过量现象的模拟。由于大量此类实验可以基于作者提出的一些关于离子与空气/水界面相互作用的简单物理模型得到解释[M. 曼丘，E. 鲁肯斯坦，《胶体与界面科学进展》105 (2003) 63；《胶体与界面科学进展》112 (2004) 109；《朗缪尔》21 (2005) 11312]，本笔记对这些模型进行了综述，目的是引起对它们的关注。
