Face-selective decoration of an organic single crystal toward photochemical devices.

Face-selective decoration of a single crystal constructed from 1-pyrenemethylammonium chloride by an anionic porphyrin dye is reported. CLSM observations indicated that the {001} face of the single crystal was selectively coated by the anionic porphyrin (TPPS). This novel achievement could be the first step for preparation of multi-component composite materials mediated by anisotropy of organic single crystals toward photochemical devices.