HCl和HBr价壳层及Br-3d内壳层激发的光学振子强度
Optical oscillator strengths for valence-shell and Br-3d inner-shell excitations of HCl and HBr.
作者信息
Li Wen-Bin, Zhu Lin-Fan, Yuan Zhen-Sheng, Liu Xiao-Jing, Xu Ke-Zun
机构信息
Hefei National Laboratory for Physical Sciences at Microscale, Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026, China.
出版信息
J Chem Phys. 2006 Oct 21;125(15):154310. doi: 10.1063/1.2357955.
Absolute optical oscillator strength density spectra for valence-shell excitations of HCl and HBr, as well as for Br-3d inner-shell excitations of HBr, have been determined by high-resolution electron-energy-loss-spectroscopy method in the dipole limit. Absolute optical oscillator strengths for the discrete transitions of HCl and HBr are reported and compared with the previous results determined by the photoabsorption method.
采用高分辨率电子能量损失光谱法，在偶极矩极限下测定了HCl和HBr价壳层激发以及HBr的Br 3d内壳层激发的绝对光学振子强度密度谱。报道了HCl和HBr离散跃迁的绝对光学振子强度，并与先前用光吸收法测定的结果进行了比较。
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