甜叶假马鞭地上部分的没药烷型倍半萜类化合物。

Bisabolane-type sesquiterpenes from the aerial parts of Lippia dulcis.

作者信息

Ono Masateru, Tsuru Tsuyoshi, Abe Hiroaki, Eto Masashi, Okawa Masafumi, Abe Fumiko, Kinjo Junei, Ikeda Tsuyoshi, Nohara Toshihiro

机构信息

School of Agriculture, Kyushu Tokai University, Minamiaso 5435, Aso, Kumamoto 869-1404, Japan.

出版信息

J Nat Prod. 2006 Oct;69(10):1417-20. doi: 10.1021/np068010m.

DOI:10.1021/np068010m

PMID:17067153

Abstract

Six new bisabolane-type sesquiterpenes, peroxylippidulcines A-C (3-5), peroxyepilippidulcine B (6), and epilippidulcines B (7) and C (8), have been isolated from the aerial parts of Lippia dulcis, along with two known bisabolane-type sesquiterpenes, seven known flavonoids, and a known triterpenoid. The structures of 3-8 were characterized on the basis of NMR, MS, specific rotation, and X-ray crystallographic analysis data and chemical evidence.

摘要

从甜叶菊地上部分分离得到6个新的没药烷型倍半萜，过氧利皮杜辛A-C（3-5）、过氧表利皮杜辛B（6）、表利皮杜辛B（7）和表利皮杜辛C（8），以及2个已知的没药烷型倍半萜、7个已知黄酮类化合物和1个已知三萜类化合物。通过核磁共振（NMR）、质谱（MS）、比旋光度以及X射线晶体学分析数据和化学证据对3-8的结构进行了表征。