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柳叶白前根中14,15-断和13,14:14,15-双断孕甾烷的糖苷。

Glycosides of 14,15-seco and 13,14:14,15-disecopregnanes from the roots of Cynanchum sublanceolatum.

作者信息

Warashina Tsutomu, Noro Tadataka

机构信息

Institute for Environmental Sciences, University of Shizuoka, Shizuoka, Japan.

出版信息

Chem Pharm Bull (Tokyo). 2006 Nov;54(11):1551-60. doi: 10.1248/cpb.54.1551.

Abstract

Thirty-two new 13,14-seco and 13,14:14,15-disecopregnane glycosides were obtained from the roots of Cynanchum sublanceolatum (Asclepiadaceae). These glycosides were confirmed to be possessing five known compounds, cynajapogenin A, glaucogenin-A, 13-hydroxycynajapogenin A, 2alpha-hydroxyanhydrohirundigenin, atratogenin A and one new pregnane, 13-epi-cynajapogenin A, as their aglycones, using both spectroscopic and chemical methods.

摘要

从柳叶白前(萝藦科)根中获得了32个新的13,14-断和13,14:14,15-双断孕甾烷糖苷。通过光谱和化学方法确定这些糖苷的苷元含有5个已知化合物,即刺瓜皂苷元A、青阳参苷元A、13-羟基刺瓜皂苷元A、2α-羟基脱水马利筋苷元、白前苷元A,以及1个新的孕甾烷13-表刺瓜皂苷元A。

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