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来自巴戟天和朝鲜巴戟天的环烯醚萜类化合物——柠檬巴戟素A、柠檬巴戟苷、尤帕苷A、尤帕苷B和巴戟天辛的结构修订

Revision of the structures of citrifolinin A, citrifolinoside, yopaaoside A, yopaaoside B, and morindacin, iridoids from Morinda citrifolia L. and Morinda coreia Ham.

作者信息

Schripsema Jan, Caprini Geisa P, Dagnino Denise

机构信息

Grupo Metabolômica, Laboratório de Ciências Químicas, Centro de Ciência e Tecnologia, Universidade Estadual do Norte Fluminense, Av. Alberto Lamego 2000, Campos dos Goytacazes, RJ BR-28015-620, Brazil.

出版信息

Org Lett. 2006 Nov 9;8(23):5337-40. doi: 10.1021/ol0622108.

DOI:10.1021/ol0622108
PMID:17078712
Abstract

[Structure: see text] Citrifolin A was revised to dehydromethoxygaertneroside (2). Citrifolinoside and yopaaoside A were found to be identical, and their structures were revised to the new structure dehydroepoxymethoxygaertneroside (5). Yopaaoside B was revised to citrifolinoside A (9), and morindacin was revised to borreriagenin (11).

摘要

[结构:见正文] 柠檬叶素A被修订为脱氢甲氧基加特纳苷(2)。发现柠檬叶苷和约帕苷A是相同的,它们的结构被修订为新结构脱氢环氧甲氧基加特纳苷(5)。约帕苷B被修订为柠檬叶苷A(9),巴戟天素被修订为巴戟素(11)。

相似文献

1
Revision of the structures of citrifolinin A, citrifolinoside, yopaaoside A, yopaaoside B, and morindacin, iridoids from Morinda citrifolia L. and Morinda coreia Ham.来自巴戟天和朝鲜巴戟天的环烯醚萜类化合物——柠檬巴戟素A、柠檬巴戟苷、尤帕苷A、尤帕苷B和巴戟天辛的结构修订
Org Lett. 2006 Nov 9;8(23):5337-40. doi: 10.1021/ol0622108.
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Bioorg Med Chem. 2003 Jun 12;11(12):2499-502. doi: 10.1016/s0968-0896(03)00180-9.
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New constituents from the leaves of Morinda citrifolia.来自巴戟天叶子的新成分。
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