catena-Poly[[[tetrakis(mu-acetato-kappa2O:O')dirhodium(II)]-mu-[1,3-bis(dimethylamino)propan-2-ol-kappa2N:N']] tetrahydrofuran hemisolvate].

作者信息

Pevec Andrej, Demsar Alojz, Aoki Katsuyuki, Turel Iztok

机构信息

Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva 5, 1000 Ljubljana, Slovenia.

出版信息

Acta Crystallogr C. 2006 Nov;62(Pt 11):m545-7. doi: 10.1107/S0108270106040972. Epub 2006 Oct 31.

In the structure of the title compound, {[Rh2(C2H3O2)4(C7H18N2O)].0.5C4H8O}n or {[Rh2(O2CMe)4(Hbdmap)].0.5C4H8O}n, where Hbdmap is 1,3-bis(dimethylamino)propan-2-ol, each Hbdmap ligand is coordinated to two [Rh2(O2CMe)4] units by two N atoms, resulting in a polymeric chain structure. The observed coordination mode of the Hbdmap molecule is unprecedented.