阐明异常的含4元吡咯环收缩氮杂卟啉类化合物作为二氢卟吩氧化过程中的中间体。
Elucidation of the extraordinary 4-membered pyrrole ring-contracted azeteoporphyrinoid as an intermediate in chlorin oxidation.
作者信息
Köpke Tillmann, Pink Maren, Zaleski Jeffrey M
机构信息
Department of Chemistry, Indiana University, Bloomington, IN, USA.
出版信息
Chem Commun (Camb). 2006 Dec 21(47):4940-2. doi: 10.1039/b611567e. Epub 2006 Oct 6.
DOI:10.1039/b611567e
PMID:17136254
Abstract
Reaction of 2,3-dioxochlorins with benzeneselenic anhydride (BSA) results in the formation of unusual ring-contracted azetine derivatives that further react with BSA to afford porpholactones.
摘要
2,3-二氧代二氢卟吩与苯亚硒酸酐（BSA）反应生成异常的环收缩氮杂环丁烷衍生物，该衍生物进一步与BSA反应得到卟吩内酯。
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