四核单金属螺旋配合物的客体依赖型反转率。
Guest-dependent inversion rate of a tetranuclear single metallohelicate.
作者信息
Akine Shigehisa, Taniguchi Takanori, Matsumoto Takashi, Nabeshima Tatsuya
机构信息
Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
出版信息
Chem Commun (Camb). 2006 Dec 21(47):4961-3. doi: 10.1039/b610641b. Epub 2006 Oct 10.
DOI:10.1039/b610641b
PMID:17136261
Abstract
Complexation of linear hexaoxime ligand H6L with Zn2+ and Mn+ (= La3+, Ba2+) afforded a tetranuclear single metallohelicate [LZn3M]n+, whose inversion rate can be modulated by the central metal Mn+.
摘要
线性六肟配体H6L与Zn2+和Mn+（=La3+、Ba2+）络合得到四核单金属螺旋体[LZn3M]n+，其反转速率可由中心金属Mn+调节。
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