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一种碗状膦作为芳基氯钯催化铃木-宫浦偶联反应中的配体:碗深度的影响

A bowl-shaped phosphine as a ligand in palladium-catalyzed Suzuki-Miyaura coupling of aryl chlorides: effect of the depth of the bowl.

作者信息

Ohta Hidetoshi, Tokunaga Makoto, Obora Yasushi, Iwai Tomohiro, Iwasawa Tetsuo, Fujihara Tetsuaki, Tsuji Yasushi

机构信息

Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, CREST, Japan Science and Technology Agency (JST), Kyoto 615-8510, Japan.

出版信息

Org Lett. 2007 Jan 4;9(1):89-92. doi: 10.1021/ol0626138.

DOI:10.1021/ol0626138
PMID:17192092
Abstract

[reaction: see text] Bowl-shaped phosphine ligands were found to be highly effective in Suzuki-Miyaura coupling of unactivated aryl chlorides, in which the depth of the bowl affected the catalytic activity considerably.

摘要

[反应:见正文] 发现碗状膦配体在未活化芳基氯的铃木-宫浦偶联反应中非常有效,其中碗的深度对催化活性有相当大的影响。

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A bowl-shaped phosphine as a ligand in palladium-catalyzed Suzuki-Miyaura coupling of aryl chlorides: effect of the depth of the bowl.一种碗状膦作为芳基氯钯催化铃木-宫浦偶联反应中的配体:碗深度的影响
Org Lett. 2007 Jan 4;9(1):89-92. doi: 10.1021/ol0626138.
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引用本文的文献

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J Mol Model. 2015 Mar;21(3):45. doi: 10.1007/s00894-015-2600-x. Epub 2015 Feb 17.
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Phosphinocyclodextrins as confining units for catalytic metal centres. Applications to carbon-carbon bond forming reactions.膦环糊精作为催化金属中心的约束单元。在碳-碳键形成反应中的应用。
Beilstein J Org Chem. 2014 Oct 15;10:2388-405. doi: 10.3762/bjoc.10.249. eCollection 2014.
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Synthesis of novel 3,5-dichloro-2-arylpyridines by palladium acetate-catalyzed ligand-free Suzuki reactions in aqueous media.在水介质中通过醋酸钯催化的无配体铃木反应合成新型3,5-二氯-2-芳基吡啶
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