Ohta Hidetoshi, Tokunaga Makoto, Obora Yasushi, Iwai Tomohiro, Iwasawa Tetsuo, Fujihara Tetsuaki, Tsuji Yasushi
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, CREST, Japan Science and Technology Agency (JST), Kyoto 615-8510, Japan.
Org Lett. 2007 Jan 4;9(1):89-92. doi: 10.1021/ol0626138.
[reaction: see text] Bowl-shaped phosphine ligands were found to be highly effective in Suzuki-Miyaura coupling of unactivated aryl chlorides, in which the depth of the bowl affected the catalytic activity considerably.
[反应:见正文] 发现碗状膦配体在未活化芳基氯的铃木-宫浦偶联反应中非常有效,其中碗的深度对催化活性有相当大的影响。