• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene.

作者信息

Brown M Kevin, May Tricia L, Baxter Carl A, Hoveyda Amir H

机构信息

Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.

出版信息

Angew Chem Int Ed Engl. 2007;46(7):1097-100. doi: 10.1002/anie.200604511.

DOI:10.1002/anie.200604511
PMID:17200971
Abstract
摘要

相似文献

1
All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene.通过手性N-杂环卡宾促进的对映选择性铜催化共轭加成反应构建全碳季碳立体中心。
Angew Chem Int Ed Engl. 2007;46(7):1097-100. doi: 10.1002/anie.200604511.
2
Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: structure and activity of an air-stable chiral Cu complex.用于高效铜催化对映选择性烯丙基烷基化反应的双齿NHC基手性配体:一种空气稳定的手性铜配合物的结构与活性
J Am Chem Soc. 2004 Sep 15;126(36):11130-1. doi: 10.1021/ja046245j.
3
A readily available chiral Ag-based N-heterocyclic carbene complex for use in efficient and highly enantioselective Ru-catalyzed olefin metathesis and Cu-catalyzed allylic alkylation reactions.一种易于获得的手性银基氮杂环卡宾配合物,用于高效且高对映选择性的钌催化烯烃复分解反应和铜催化烯丙基烷基化反应。
J Am Chem Soc. 2005 May 11;127(18):6877-82. doi: 10.1021/ja050179j.
4
A practical method for enantioselective synthesis of all-carbon quaternary stereogenic centers through NHC-Cu-catalyzed conjugate additions of alkyl- and arylzinc reagents to beta-substituted cyclic enones.一种通过NHC-Cu催化的烷基锌和芳基锌试剂与β-取代环状烯酮的共轭加成对全碳季碳立体中心进行对映选择性合成的实用方法。
J Am Chem Soc. 2006 Jun 7;128(22):7182-4. doi: 10.1021/ja062061o.
5
Monodentate non-C(2)-symmetric chiral N-heterocyclic carbene complexes for enantioselective synthesis. Cu-catalyzed conjugate additions of aryl- and alkenylsilylfluorides to cyclic enones.用于对映选择性合成的单齿非C(2)对称手性N-杂环卡宾配合物。铜催化芳基和烯基甲硅烷基氟化物对环状烯酮的共轭加成反应。
J Org Chem. 2009 Jun 19;74(12):4455-62. doi: 10.1021/jo900589x.
6
Lewis base activation of grignard reagents with N-heterocyclic carbenes. Cu-free catalytic enantioselective additions to gamma-chloro-alpha,beta-unsaturated esters.用N-杂环卡宾对格氏试剂进行路易斯碱活化。无铜催化对γ-氯-α,β-不饱和酯的对映选择性加成反应。
J Am Chem Soc. 2006 Dec 13;128(49):15604-5. doi: 10.1021/ja067456m.
7
Enantioselective synthesis of nitroalkanes bearing all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions.通过铜催化的不对称共轭加成反应对含有全碳季碳手性中心的硝基烷烃进行对映选择性合成。
J Am Chem Soc. 2005 Apr 6;127(13):4584-5. doi: 10.1021/ja050800f.
8
Catalytic enantioselective alkylations of tetrasubstituted olefins. Synthesis of all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to enones.四取代烯烃的催化对映选择性烷基化反应。通过铜催化的烷基锌试剂与烯酮的不对称共轭加成反应合成全碳季碳手性中心。
J Am Chem Soc. 2005 Nov 2;127(43):14988-9. doi: 10.1021/ja0553811.
9
Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enones.通过铜催化芳基和烷基铝试剂对无环三取代烯酮的共轭加成实现季碳立体中心的对映选择性合成。
Angew Chem Int Ed Engl. 2013 Jul 29;52(31):8156-9. doi: 10.1002/anie.201304035. Epub 2013 Jun 18.
10
Chiral N-heterocyclic carbene-copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides: steric and electronic effects on γ-selectivity.手性 N-杂环卡宾-铜(I)催化脂肪族烯丙基溴的不对称烯丙基芳基化反应:γ-选择性的立体和电子效应。
J Org Chem. 2011 Mar 4;76(5):1398-408. doi: 10.1021/jo102386s. Epub 2011 Jan 25.

引用本文的文献

1
Design Approaches That Utilize Ionic Interactions to Control Selectivity in Transition Metal Catalysis.利用离子相互作用控制过渡金属催化选择性的设计方法。
Chem Rev. 2025 Mar 12;125(5):2846-2907. doi: 10.1021/acs.chemrev.4c00849. Epub 2025 Feb 28.
2
Finding activity through rigidity: syntheses of natural products containing tricyclic bridgehead carbon centers.通过刚性寻找活性:含有三环桥碳原子中心的天然产物的合成。
Nat Prod Rep. 2023 Aug 16;40(8):1393-1431. doi: 10.1039/d3np00008g.
3
Mechanochemical solid state synthesis of copper(I)/NHC complexes with KPO.
采用机械化学固态法合成含KPO的铜(I)/氮杂环卡宾配合物。
Beilstein J Org Chem. 2023 Apr 14;19:440-447. doi: 10.3762/bjoc.19.34. eCollection 2023.
4
Discussion Addendum for: Preparation of ()--ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids.关于“()-丁基吡啶氧化物的制备及钯催化芳基硼酸的不对称共轭加成”的讨论附录
Organic Synth. 2021;98:117-130. doi: 10.15227/orgsyn.098.0117.
5
Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands.涉及双齿氮杂环卡宾配体的催化作用的最新进展
Molecules. 2021 Dec 24;27(1):95. doi: 10.3390/molecules27010095.
6
Synthesis of Cyclohexane-Angularly-Fused Triquinanes.环己烷角稠合三环烷的合成
Synthesis (Stuttg). 2021;53(3):475-488. doi: 10.1055/s-0040-1705953. Epub 2020 Nov 3.
7
Contiguous Quaternary Carbons: A Selection of Total Syntheses.连续的四元碳:全合成选择。
Molecules. 2020 Aug 24;25(17):3841. doi: 10.3390/molecules25173841.
8
Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C-C, C-B, C-H, and C-Si Bonds.磺酸酯 N-杂环卡宾-铜配合物:手性合成 C-C、C-B、C-H 和 C-Si 键的高效独特催化剂。
Angew Chem Int Ed Engl. 2020 Nov 23;59(48):21304-21359. doi: 10.1002/anie.202003755. Epub 2020 Aug 26.
9
A Concise Total Synthesis of (+)-Waihoensene Guided by Quaternary Center Analysis.基于立体中心分析指导的 (+)-Waihoensene 的简洁全合成。
Angew Chem Int Ed Engl. 2020 Aug 3;59(32):13521-13525. doi: 10.1002/anie.202004177. Epub 2020 Jun 3.
10
Preparation of ()--ButylPyOx and Palladium-catalyzed Asymmetric Conjugate Addition of Arylboronic Acids.()-丁基吡啶氧化物的制备及钯催化芳基硼酸的不对称共轭加成反应
Organic Synth. 2016;92. doi: 10.1002/0471264229.os092.19. Epub 2016 Mar 4.