Barluenga José, Moriel Patricia, Aznar Fernando, Valdés Carlos
Instituto Universitario de Química OrganometAlica Enrique Moles, Universidad de Oviedo, JuliAn Clavería 8, Oviedo 33006, Spain.
Org Lett. 2007 Jan 18;9(2):275-8. doi: 10.1021/ol062726r.
N-Boc-N-alkenylhydrazines, an almost unknown type of compounds, have been prepared with high to moderate yields via palladium-catalyzed cross-coupling between alkenyl halides and tert-butyl carbazate. The present methodology represents the first general way to access this highly functionalized and unusual type of hydrazines. [reaction: see text].
N-叔丁氧羰基-N-烯基肼是一类几乎不为人知的化合物，通过钯催化的卤代烯烃与叔丁基肼基甲酸酯之间的交叉偶联反应，已以中等到较高的产率制备得到。目前的方法是获得这种高度官能化且不同寻常的肼类化合物的首个通用方法。[反应：见正文]
