Surry David S, Buchwald Stephen L
Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA. ; Tel: +1-617-253-1885.
Chem Sci. 2011;2(1):27-50. doi: 10.1039/C0SC00331J.
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this class for the most commonly encountered and practically important substrate combinations.
二烷基联芳基膦是用于钯催化胺化反应的一类重要配体,并已在一系列情况下得到应用。本综述旨在帮助读者针对最常见且实际重要的底物组合,选择此类反应的最佳反应条件和配体。