用于惰性烃催化官能化的卡宾插入方法：无经典的C-H活化，但有高效的C-H官能化。

The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: no classical C-H activation, but efficient C-H functionalization.

作者信息

Díaz-Requejo M Mar, Belderrain Tomás R, Nicasio M Carmen, Pérez Pedro J

机构信息

Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Universidad de Huelva, Campus de El Carmen, 21007, Huelva, Spain.

出版信息

Dalton Trans. 2006 Dec 21(47):5559-66. doi: 10.1039/b610183f. Epub 2006 Oct 30.

DOI:10.1039/b610183f

PMID:17225892

Abstract

This contribution intends to highlight the use of the metal-catalyzed functionalization of unreactive carbon-hydrogen bonds by the carbene insertion methodology, that employs diazo compounds as the carbene source.

摘要

本论文旨在强调通过卡宾插入方法实现未反应碳氢键的金属催化官能团化的应用，该方法采用重氮化合物作为卡宾源。