印楝素的合成研究：具有完整官能团的AB环的高效立体选择性构建。 - Suppr

Synthetic study towards azadirachtin: an efficient and stereoselective construction of the AB rings with full functionality.

作者信息

Watanabe Hidenori, Mori Naoki, Itoh Daisuke, Kitahara Takeshi, Mori Kenji

机构信息

Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan.

出版信息

Angew Chem Int Ed Engl. 2007;46(9):1512-6. doi: 10.1002/anie.200604097.

DOI:10.1002/anie.200604097

PMID:17226885

Abstract

摘要

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Synthetic study towards azadirachtin: an efficient and stereoselective construction of the AB rings with full functionality.

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Cascade Grignard Addition: Propargyl Claisen Rearrangement for the Stereoselective Synthesis of α-Allene Quaternary Centers in Cyclohexanones.

Org Lett. 2025 Jul 25;27(29):7767-7772. doi: 10.1021/acs.orglett.5c02006. Epub 2025 Jun 18.

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Synthetic study towards azadirachtin: an efficient and stereoselective construction of the AB rings with full functionality.

Angew Chem Int Ed Engl. 2007;46(9):1512-6. doi: 10.1002/anie.200604097.

Total synthesis of azadirachtin--finally completed after 22 years.

Angew Chem Int Ed Engl. 2008;47(1):34-7. doi: 10.1002/anie.200703814.

Synthesis of natural products from the Indian neem tree Azadirachta indica.

Org Lett. 2008 Feb 21;10(4):569-72. doi: 10.1021/ol7027898. Epub 2008 Jan 15.

The azadirachtin story.

Angew Chem Int Ed Engl. 2008;47(49):9402-29. doi: 10.1002/anie.200802675.

Studies towards the synthesis of azadirachtin: enantioselective entry into the azadirachtin framework through cascade reactions.

Angew Chem Int Ed Engl. 2003 Aug 11;42(31):3637-42. doi: 10.1002/anie.200351744.

Model studies towards azadirachtin: part 1. Construction of the crowded C8-C14 bond by radical chemistry.

Angew Chem Int Ed Engl. 2002 Jun 17;41(12):2103-6.

Azadirachtin derivatives from seed kernels of Azadirachta excelsa.

J Nat Prod. 2005 Jul;68(7):1047-50. doi: 10.1021/np050064t.

Model studies towards azadirachtin: part 2. Construction of the crowded C8-C14 bond by transition metal chemistry.

Angew Chem Int Ed Engl. 2002 Jun 17;41(12):2107-10.

Second-generation synthesis of azadirachtin: a concise preparation of the propargylic mesylate fragment.

Angew Chem Int Ed Engl. 2009;48(7):1317-20. doi: 10.1002/anie.200805395.

Semi-synthetic modification of nimbolide to 6-homodesacetylnimbin and 6-desacetylnimbin and their cytotoxic studies.

J Asian Nat Prod Res. 2007 Jan-Feb;9(1):73-8. doi: 10.1080/10286020500383742.

引用本文的文献

Cascade Grignard Addition: Propargyl Claisen Rearrangement for the Stereoselective Synthesis of α-Allene Quaternary Centers in Cyclohexanones.

Org Lett. 2025 Jul 25;27(29):7767-7772. doi: 10.1021/acs.orglett.5c02006. Epub 2025 Jun 18.

Synthetic study towards azadirachtin: an efficient and stereoselective construction of the AB rings with full functionality.

作者信息

Watanabe Hidenori, Mori Naoki, Itoh Daisuke, Kitahara Takeshi, Mori Kenji

机构信息

Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan.

出版信息

Angew Chem Int Ed Engl. 2007;46(9):1512-6. doi: 10.1002/anie.200604097.

DOI:10.1002/anie.200604097

PMID:17226885

Abstract

摘要

Synthetic study towards azadirachtin: an efficient and stereoselective construction of the AB rings with full functionality.

作者信息

机构信息

出版信息

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Synthetic study towards azadirachtin: an efficient and stereoselective construction of the AB rings with full functionality.

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