Suppr超能文献

碳纳米管分散对聚苯胺气体传感器CO气敏特性的影响

The effect of carbon nanotube dispersion on CO gas sensing characteristics of polyaniline gas sensor.

作者信息

Wanna Y, Srisukhumbowornchai N, Tuantranont A, Wisitsoraat A, Thavarungkul N, Singjai P

机构信息

National Nanotechnology Center (NANOTEC), 111 Thailand Science Park, Klong Luang, Pathumthani 12120, Thailand.

出版信息

J Nanosci Nanotechnol. 2006 Dec;6(12):3893-6. doi: 10.1166/jnn.2006.675.

Abstract

Polyaniline is one of the most promising conducting polymers for gas sensing applications due to its relatively high stability and n or p type doping capability. However, the conventionally doped polyaniline still exhibits relatively high resistivity, which causes difficulty in gas sensing measurement. In this work, the effect of carbon nanotube (CNT) dispersion on CO gas sensing characteristics of polyaniline gas sensor is studied. The carbon nanotube was synthesized by Chemical Vapor Deposition (CVD) using acetylene and argon gases at 600 degrees C. The Maleic acid doped Emeradine based polyaniline was synthesized by chemical polymerization of aniline. CNT was then added and dispersed in the solution by ultrasonication and deposited on to interdigitated AI electrode by solvent casting. The sensors were tested for CO sensing at room temperature with CO concentrations in the range of 100-1000 ppm. It was found that the gas sensing characteristics of polyaniline based gas sensor were considerably improved with the inclusion of CNT in polyaniline. The sensitivity was increased and response/recovery times were reduced by more than the factor of 2. The results, therefore, suggest that the inclusion of CNT in MA-doped polyaniline is a promising method for achieving a conductive polymer gas sensor with good sensitivity, fast response, low-concentration detection and room-operating-temperature capability.

摘要

聚苯胺因其相对较高的稳定性和n型或p型掺杂能力,是气体传感应用中最有前途的导电聚合物之一。然而,传统掺杂的聚苯胺仍然表现出相对较高的电阻率,这给气体传感测量带来了困难。在这项工作中,研究了碳纳米管(CNT)分散对聚苯胺气体传感器CO气体传感特性的影响。碳纳米管是通过化学气相沉积(CVD)在600℃下使用乙炔和氩气合成的。马来酸掺杂的基于Emeradine的聚苯胺是通过苯胺的化学聚合合成的。然后加入碳纳米管并通过超声分散在溶液中,并通过溶剂浇铸沉积在叉指式铝电极上。在室温下对传感器进行CO传感测试,CO浓度范围为100-1000ppm。结果发现,在聚苯胺中加入碳纳米管后,基于聚苯胺的气体传感器的气敏特性得到了显著改善。灵敏度提高,响应/恢复时间缩短了两倍多。因此,结果表明,在马来酸掺杂的聚苯胺中加入碳纳米管是实现具有良好灵敏度、快速响应、低浓度检测和室温操作温度能力的导电聚合物气体传感器的一种有前途的方法。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验