Farea Mohammed O, Alhadlaq Hisham A, Alaizeri ZabnAllah M, Ahmed Abdullah A A, Sallam Mohyeddine O, Ahamed Maqusood
Department of Physics, Faculty of Science, Mansoura University, Mansoura 35516, Egypt.
Department of Physics and Astronomy, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
ACS Omega. 2022 Jun 21;7(26):22492-22499. doi: 10.1021/acsomega.2c01664. eCollection 2022 Jul 5.
In this work, the carbon monoxide (CO) detection property of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)/poly(-anisidine) (PEDOT:PSS/PPA) nanocomposite was systematically investigated at room temperature. The PEDOT:PSS/PPA nanocomposite was synthesized by the cost-effective "in situ chemical oxidation polymerization" technique. The electric, optical, spectroscopic, and structural properties of the as-prepared nanomaterials were analyzed with -, UV-vis, Raman, Fourier transform infrared (FTIR), and X-ray diffraction (XRD) spectroscopies. Topological investigations of materials were conducted by atomic force microscopy (AFM). The gas-sensing performance of the PEDOT:PSS/PPA and PEDOT:PSS nanocomposites toward CO gas in the concentration range of 50-300 ppm at room temperature was explored, and their performances were compared. The PEDOT:PSS/PPA sensor shows a perfectly linear response to different concentrations (50-300 ppm) of CO gas ( = 0.9885), and the response time and recovery time of the CO gas sensor (100 ppm) can be about 58 and 61 s, respectively, showing high sensitivity to CO gas and rapid response recovery with outstanding stability. Thus, the PEDOT:PSS/PPA-based sensors, with their impressive sensing performance, may give assurance for future high-performance CO-sensing applications.
在本工作中,系统研究了聚(3,4-乙撑二氧噻吩)-聚(苯乙烯磺酸盐)/聚(对茴香胺)(PEDOT:PSS/PPA)纳米复合材料在室温下对一氧化碳(CO)的检测性能。PEDOT:PSS/PPA纳米复合材料采用经济高效的“原位化学氧化聚合”技术合成。利用扫描电子显微镜、紫外可见光谱、拉曼光谱、傅里叶变换红外(FTIR)光谱和X射线衍射(XRD)光谱对所制备纳米材料的电学、光学、光谱和结构性质进行了分析。通过原子力显微镜(AFM)对材料进行了拓扑研究。探索了PEDOT:PSS/PPA和PEDOT:PSS纳米复合材料在室温下对浓度范围为50-300 ppm的CO气体的气敏性能,并对它们的性能进行了比较。PEDOT:PSS/PPA传感器对不同浓度(50-300 ppm)的CO气体表现出完美的线性响应(R² = 0.9885),CO气体传感器(100 ppm)的响应时间和恢复时间分别约为58和61 s,对CO气体表现出高灵敏度,响应恢复迅速且稳定性出色。因此,基于PEDOT:PSS/PPA的传感器具有令人印象深刻的传感性能,可为未来高性能CO传感应用提供保障。