中国蛤蜊（Mactra chinensis）中岩藻黄质和岩藻黄醇酯的特性分析

Characterization of fucoxanthin and fucoxanthinol esters in the Chinese surf clam, Mactra chinensis.

作者信息

Maoka Takashi, Fujiwara Yasuhiro, Hashimoto Keiji, Akimoto Naoshige

机构信息

Research Institute for Production Development, 15 Shimogamo-morimoto-cho, Sakyo-ku, Kyoto 606-0805, Japan.

出版信息

J Agric Food Chem. 2007 Feb 21;55(4):1563-7. doi: 10.1021/jf063139n. Epub 2007 Jan 31.

DOI:10.1021/jf063139n

PMID:17263549

Abstract

Fucoxanthin and fucoxanthinol fatty acid esters in the clam, Mactra chinensis, were characterized on the basis of 1H NMR and FAB-MS spectra. 1H NMR revealed that the hydroxy group at C-3 in fucoxanthin and fucoxanthinol was acylated. 3'-O-Acylated compounds such as fucoxanthinol 3'-ester or fucoxanthinol 3,3'-diester were not found in the clam. The fatty acids esterified with fucoxanthin and fucoxanthinol were identified as C24:6, C22:5, C22:6, C20:5, C20:0, C20:1, C18:0, C18:1, C16:0, C16:1, and C14:0 by FAB-MS data.

摘要

基于1H NMR和FAB-MS光谱对中国蛤蜊（Mactra chinensis）中的岩藻黄质和岩藻黄醇脂肪酸酯进行了表征。1H NMR显示，岩藻黄质和岩藻黄醇中C-3位的羟基被酰化。在蛤蜊中未发现3'-O-酰化化合物，如岩藻黄醇3'-酯或岩藻黄醇3,3'-二酯。通过FAB-MS数据确定，与岩藻黄质和岩藻黄醇酯化的脂肪酸为C24:6、C22:5、C22:6、C20:5、C20:0、C20:1、C18:0、C18:1、C16:0、C16:1和C14:0。