Hermanns H-G, Felderhof B U
gesco Consulting Engineers Limited, Niederlassung Deutschland, Am Hecklehamm 6, 76549 Hügelsheim, Germany.
J Chem Phys. 2007 Jan 28;126(4):044902. doi: 10.1063/1.2428303.
The long-time translational and rotational Brownian motion of a sphere in a suspension of hard spheres is studied on the basis of the linearized Navier-Stokes equations and the fluctuation-dissipation theorem. It is shown that for the rotational long-time coefficient an effective medium conjecture is incorrect. There are short-range velocity correlations that decay at the same rate as the macroscopic flow pattern used in the effective medium conjecture. An estimate of the short-range correction is made on the basis of the pair term in the cluster expansion of the rotational admittance.
基于线性化的纳维-斯托克斯方程和涨落耗散定理,研究了球体在硬球悬浮液中的长时间平移和旋转布朗运动。结果表明,对于旋转长时间系数,有效介质猜想是不正确的。存在短程速度相关性,其衰减速率与有效介质猜想中使用的宏观流型相同。基于旋转导纳的簇展开中的对项,对短程修正进行了估计。