通过添加有机硼引发的顺序碳硼氢化反应形成碳环。
Formation of carbocycles through sequential carborhodation triggered by addition of organoborons.
作者信息
Miura Tomoya, Murakami Masahiro
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, 615-8510, Japan.
出版信息
Chem Commun (Camb). 2007 Jan 21(3):217-24. doi: 10.1039/b609991b. Epub 2006 Aug 24.
DOI:10.1039/b609991b
PMID:17299619
Abstract
This article highlights recent developments in the formation of carbocycles via multiple carborhodation steps triggered by the rhodium-catalysed intermolecular addition of organoborons. Various types of cascade reactions have been developed to demonstrate that multiple carborhodation steps can precede potentially competing processes such as protonolysis.
摘要
本文重点介绍了通过铑催化的有机硼分子间加成引发的多步碳硼氢化反应形成碳环化合物的最新进展。已经开发了各种类型的串联反应，以证明多步碳硼氢化反应可以先于诸如质子解等潜在的竞争过程。
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