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通过在边缘放置硒来微调开孔富勒烯的孔口尺寸:分子氢的插入/释放。

Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen.

作者信息

Chuang Shih-Ching, Murata Yasujiro, Murata Michihisa, Mori Sadayuki, Maeda Shuhei, Tanabe Fumiyuki, Komatsu Koichi

机构信息

Institute for Chemical Research, Kyoto University, Uji, Kyoto, 611-0011, Japan.

出版信息

Chem Commun (Camb). 2007 Mar 28(12):1278-80. doi: 10.1039/b616478a. Epub 2007 Jan 16.

DOI:10.1039/b616478a
PMID:17356782
Abstract

A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.

摘要

一种新合成的在13元环孔边缘含有硒的开孔富勒烯,使得氢插入的条件更为温和,并且氢释放速率约为其含硫类似物的三倍。

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Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen.通过在边缘放置硒来微调开孔富勒烯的孔口尺寸:分子氢的插入/释放。
Chem Commun (Camb). 2007 Mar 28(12):1278-80. doi: 10.1039/b616478a. Epub 2007 Jan 16.
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引用本文的文献

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Synthesis of endohedral fullerenes by molecular surgery.通过分子手术合成内嵌富勒烯。
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