作为新型手性二烯配体的C2对称四氢并五苯的设计，用于铑催化的N-对甲苯磺酰基芳基亚胺与芳基硼酸的高度对映选择性芳基化反应。 - Suppr

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超能文献

Design of C2-symmetric tetrahydropentalenes as new chiral diene ligands for highly enantioselective Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids.

作者信息

Wang Zhi-Qian, Feng Chen-Guo, Xu Ming-Hua, Lin Guo-Qiang

机构信息

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China.

出版信息

J Am Chem Soc. 2007 May 2;129(17):5336-7. doi: 10.1021/ja0710914. Epub 2007 Apr 11.

DOI:10.1021/ja0710914

PMID:17425322

Abstract

摘要

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Design of C2-symmetric tetrahydropentalenes as new chiral diene ligands for highly enantioselective Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids.作为新型手性二烯配体的C2对称四氢并五苯的设计，用于铑催化的N-对甲苯磺酰基芳基亚胺与芳基硼酸的高度对映选择性芳基化反应。

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