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一种手性铑催化的芳基硼酸与烯基氮杂芳烃加成反应的第二代配体。

A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes.

机构信息

EaStCHEM, School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, UK.

出版信息

Chem Commun (Camb). 2014 Mar 18;50(22):2865-8. doi: 10.1039/c4cc00340c. Epub 2014 Feb 3.

DOI:10.1039/c4cc00340c
PMID:24488116
Abstract

A 2,4,6-trialkylanilide-containing chiral diene has been identified as a superior ligand for the enantioselective rhodium-catalyzed arylation of alkenylazaarenes with arylboronic acids.

摘要

已确定一种含 2,4,6-三烷基亚苯胺的手性二烯为优越配体，用于手性铑催化的烯基氮杂芳烃与芳基硼酸的对映选择性芳基化反应。

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