Rosenfeld P E, Clark J J J, Hensley A R, Suftet I H
Soil Water Air Protection Enterprise, 201 Wilshire Blvd., Second Floor, Santa Monica, CA 90401, USA.
Water Sci Technol. 2007;55(5):345-57. doi: 10.2166/wst.2007.197.
Odorants are released during the decomposition of organic waste at compost treatment plants. Composting releases volatile organic chemicals (VOCs), including alcohols, aldehydes, volatile fatty acids, ammonia and other nitrogen compounds, senobiotic solvents, and various sulphur compounds into the environment as categorised by a compost odor wheel. Each odorant possesses a characteristic odour signature--quality and threshold as well as a tosicity value. This paper presents data relating the human odour detection limit to human health threshold criteria developed by the National Institute for Occupational Safety and Health, Occupational Satety and Health Administration, the United States Environmental Protection Agency Region 9 and the World Health Organisation. This comparison indicates that: (1) the human odour threshold concentrations (OTO) for most compost odorants are far lower than their respective human health risk (regulatory) threshold values, (2) several compost odorants have OTC that are below some of their respective regulatory thresholds and above others (i.e. dimethyl amine, formic acid acetone, ethyl benzene and toluene) and (3) only the VOCs probably present as contaminants in the raw composting material have OTC greater than all of its regulatory thresholds (i.e. benzene). Benzene is the most hazardous VOC associated with compoating and should be monitored.
在堆肥处理厂中,有机废物分解过程会释放出气味物质。堆肥过程会向环境中释放挥发性有机化合物(VOCs),包括酒精、醛类、挥发性脂肪酸、氨和其他含氮化合物、半挥发性溶剂以及各种硫化合物,这些都在堆肥气味轮中有所分类。每种气味物质都具有独特的气味特征——质量、阈值以及毒性值。本文呈现了将人类气味检测极限与美国国家职业安全与健康研究所、职业安全与健康管理局、美国环境保护局第9区域以及世界卫生组织制定的人类健康阈值标准相关联的数据。这种比较表明:(1)大多数堆肥气味物质的人类气味阈值浓度(OTO)远低于其各自的人类健康风险(监管)阈值;(2)几种堆肥气味物质的OTO低于其部分各自的监管阈值且高于其他阈值(即二甲胺、甲酸、丙酮、乙苯和甲苯);(3)只有可能作为原始堆肥材料中污染物存在的VOCs的OTO大于其所有监管阈值(即苯)。苯是与堆肥相关的最危险的VOCs,应予以监测。