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污水污泥堆肥过程中的气味成分分析与气味指标选择

Odor composition analysis and odor indicator selection during sewage sludge composting.

作者信息

Zhu Yan-Li, Zheng Guo-di, Gao Ding, Chen Tong-Bin, Wu Fang-Kun, Niu Ming-Jie, Zou Ke-Hua

机构信息

a Center for Environmental Remediation, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences , Beijing , People's Republic of China.

b State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences , Beijing , People's Republic of China.

出版信息

J Air Waste Manag Assoc. 2016 Sep;66(9):930-40. doi: 10.1080/10962247.2016.1188865.

Abstract

UNLABELLED

On the basis of total temperature increase, normal dehydration, and maturity, the odor compositions of surface and internal piles in a well-run sewage sludge compost plant were analyzed using gas chromatography-mass spectrometry with a liquid nitrogen cooling system and a portable odor detector. Approximately 80 types of substances were detected, including 2 volatile inorganic compounds, 4 sulfur organic compounds, 16 benzenes, 27 alkanes, 15 alkenes, and 19 halogenated compounds. Most pollutants were mainly produced in the mesophilic and pre-thermophilic periods. The sulfur volatile organic compounds contributed significantly to odor and should be controlled primarily. Treatment strategies should be based on the properties of sulfur organic compounds. Hydrogen sulfide, methyl mercaptan, dimethyl disulfide, dimethyl sulfide, ammonia, and carbon disulfide were selected as core indicators. Ammonia, hydrogen sulfide, carbon disulfide, dimethyl disulfide, methyl mercaptan, dimethylbenzene, phenylpropane, and isopentane were designated as concentration indicators. Benzene, m-xylene, p-xylene, dimethylbenzene, dichloromethane, toluene, chlorobenzene, trichloromethane, carbon tetrachloride, and ethylbenzene were selected as health indicators. According to the principle of odor pollution indicator selection, dimethyl disulfide was selected as an odor pollution indicator of sewage sludge composting. Monitoring dimethyl disulfide provides a highly scientific method for modeling and evaluating odor pollution from sewage sludge composting facilities.

IMPLICATIONS

Composting is one of the most important methods for sewage sludge treatment and improving the low organic matter content of many agricultural soils. However, odors are inevitably produced during the composting process. Understanding the production and emission patterns of odors is important for odor control and treatment. Core indicators, concentration indicators, and health indicators provide an index system to odor evaluation. An odor pollution indicator provides theoretical support for further modelling and evaluating odor pollution from sewage sludge composting facilities.

摘要

未标注

基于总温度升高、正常脱水和成熟度,使用带有液氮冷却系统的气相色谱 - 质谱联用仪和便携式气味探测器,对一家运行良好的污水污泥堆肥厂中表层和内部堆肥的气味成分进行了分析。检测到约80种物质,包括2种挥发性无机化合物、4种含硫有机化合物、16种苯类、27种烷烃、15种烯烃和19种卤代化合物。大多数污染物主要在中温期和嗜热前期产生。含硫挥发性有机化合物对气味贡献显著,应作为主要控制对象。处理策略应基于含硫有机化合物的性质。选择硫化氢、甲硫醇、二甲基二硫醚、二甲基硫醚、氨和二硫化碳作为核心指标。将氨、硫化氢、二硫化碳、二甲基二硫醚、甲硫醇、二甲苯、苯丙烷和异戊烷指定为浓度指标。选择苯、间二甲苯、对二甲苯、二甲苯、二氯甲烷、甲苯、氯苯、三氯甲烷、四氯化碳和乙苯作为健康指标。根据气味污染指标选择原则,选择二甲基二硫醚作为污水污泥堆肥的气味污染指标。监测二甲基二硫醚为模拟和评估污水污泥堆肥设施的气味污染提供了一种高度科学的方法。

启示

堆肥是污水污泥处理以及提高许多农业土壤低有机质含量的最重要方法之一。然而,堆肥过程中不可避免地会产生气味。了解气味的产生和排放模式对于气味控制和处理很重要。核心指标、浓度指标和健康指标为气味评估提供了一个指标体系。气味污染指标为进一步模拟和评估污水污泥堆肥设施的气味污染提供了理论支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4406/5062037/54ad4e38ba43/uawm_a_1188865_f0001_b.jpg

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