一种士的宁碱的合成方法。
An approach to the synthesis of stenine.
作者信息
Zhu Liang, Lauchli Ryan, Loo Mandy, Shea Kenneth J
机构信息
Department of Chemistry, Natural Sciences 1102, University of California Irvine, Irvine, California 92697, USA.
出版信息
Org Lett. 2007 Jun 7;9(12):2269-71. doi: 10.1021/ol070397c. Epub 2007 May 10.
PMID:17489596
Abstract
A type 2 N-acylnitroso intramolecular Diels-Alder reaction followed by reductive N-O bond cleavage formed the B and C rings of the Stemona alkaloid stenine. Further elaboration provided the functionalized tricyclic core.
摘要
一个2型N-酰基亚硝基分子内狄尔斯-阿尔德反应，随后进行还原性N-O键断裂，形成了百部生物碱百部碱的B环和C环。进一步的修饰得到了官能化的三环核心。
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