• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

硫属元素供体与双卤代物/类卤代物之间的反应：产物类型及其傅里叶变换拉曼光谱表征。

Reactions Between Chalcogen Donors and Dihalogens/Interalogens: Typology of Products and Their Characterization by FT-Raman Spectroscopy.

机构信息

Dipartimento di Chimica Inorganica ed Analitica, Università degli Studi di Cagliari, S.S. 554 Bivio per Sestu, 09042 Monserrato, (CA), Italy.

出版信息

Bioinorg Chem Appl. 2006;2006:58937. doi: 10.1155/BCA/2006/58937. Epub 2006 Dec 31.

DOI:10.1155/BCA/2006/58937
PMID:17497008
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1800915/
Abstract

The chemical bond and structural features for the most important classes of solid products obtained by reacting chalcogen donors with dihalogens and interhalogens are reviewed. Particular attention is paid to the information the FT-Raman spectroscopy can confidently give about each structural motif considered in the absence of X-ray structural analyses.

摘要

本文综述了用硫属元素给体与二卤和多卤反应得到的最重要的固体产物的化学键和结构特征。特别关注在没有 X 射线结构分析的情况下，傅里叶变换拉曼光谱可以对所考虑的每个结构基元提供的信息。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/9b8ce0aa16f7/BCA2006-58937.011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/c8778007d1a2/BCA2006-58937.001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/1c611ce336ba/BCA2006-58937.002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/32668a4340ce/BCA2006-58937.003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/7a9a6a441377/BCA2006-58937.004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/c6b47345c10f/BCA2006-58937.005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/b9b33807bc5c/BCA2006-58937.006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/8c6643c4907e/BCA2006-58937.007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/9327e13d1641/BCA2006-58937.008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/2872f24d19ba/BCA2006-58937.009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/88f5b392202b/BCA2006-58937.010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/9b8ce0aa16f7/BCA2006-58937.011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/c8778007d1a2/BCA2006-58937.001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/1c611ce336ba/BCA2006-58937.002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/32668a4340ce/BCA2006-58937.003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/7a9a6a441377/BCA2006-58937.004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/c6b47345c10f/BCA2006-58937.005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/b9b33807bc5c/BCA2006-58937.006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/8c6643c4907e/BCA2006-58937.007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/9327e13d1641/BCA2006-58937.008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/2872f24d19ba/BCA2006-58937.009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/88f5b392202b/BCA2006-58937.010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d501/1800915/9b8ce0aa16f7/BCA2006-58937.011.jpg

相似文献

1
Reactions Between Chalcogen Donors and Dihalogens/Interalogens: Typology of Products and Their Characterization by FT-Raman Spectroscopy.硫属元素供体与双卤代物/类卤代物之间的反应：产物类型及其傅里叶变换拉曼光谱表征。
Bioinorg Chem Appl. 2006;2006:58937. doi: 10.1155/BCA/2006/58937. Epub 2006 Dec 31.
2
Direct investigation of chalcogen bonds by multinuclear solid-state magnetic resonance and vibrational spectroscopy.通过多核固态磁共振和振动光谱对硫族元素键进行直接研究。
Phys Chem Chem Phys. 2020 Feb 19;22(7):3817-3824. doi: 10.1039/c9cp06267j.
3
Hypervalent adducts of chalcogen-containing peri-substituted naphthalenes; reactions of sulfur, selenium, and tellurium with dihalogens.含硫、硒和碲的五元环取代萘的高价加合物；卤素与二卤代物的反应。
Inorg Chem. 2010 Aug 16;49(16):7577-96. doi: 10.1021/ic101086h.
4
Se and Te solid-state NMR and X-ray diffraction structural study of chalcogen-bonded 3,4-dicyano-1,2,5-chalcogenodiazole cocrystals.硒碲键合 3,4-二氰基-1,2,5-硫氮杂二唑共晶的固态核磁共振和 X 射线衍射结构研究。
Acta Crystallogr C Struct Chem. 2022 Oct 1;78(Pt 10):517-523. doi: 10.1107/S2053229622008518. Epub 2022 Sep 10.
5
A unique case of oxidative addition of interhalogens IX (X=Cl, Br) to organodiselone ligands: nature of the chemical bonding in asymmetric I-Se-X polarised hypervalent systems.一个独特的例子，涉及到 IX 类（X=Cl，Br）的间卤素与有机二硒烯配体的氧化加成：在非对称 I-Se-X 极化的高价体系中化学键的本质。
Chemistry. 2011 Oct 4;17(41):11497-514. doi: 10.1002/chem.201100970. Epub 2011 Aug 25.
6
Reactivity of fluoro-substituted bis(thiocarbonyl) donors with diiodine: an XRD, FT-Raman, and DFT investigation.氟取代双(硫代羰基)给体与二碘反应的研究：XRD、FT-Raman 和 DFT 研究。
Chem Asian J. 2013 Dec;8(12):3071-8. doi: 10.1002/asia.201300693. Epub 2013 Sep 11.
7
Double Chalcogen Bonds: Crystal Engineering Stratagems via Diffraction and Multinuclear Solid-State Magnetic Resonance Spectroscopy.双硫属元素键：通过衍射和多核磁共振固态光谱的晶体工程策略
Chemistry. 2020 Mar 12;26(15):3275-3286. doi: 10.1002/chem.201904795. Epub 2020 Jan 30.
8
Exploiting the σ-Hole Concept: An Infrared and Raman-Based Characterization of the S⋅⋅⋅O Chalcogen Bond between 2,2,4,4-Tetrafluoro-1,3-dithiethane and Dimethyl Ether.利用σ-空穴概念：基于红外和拉曼光谱对2,2,4,4-四氟-1,3-二硫杂环丁烷与二甲醚之间S⋅⋅⋅O硫族元素键的表征
Chemistry. 2017 Dec 6;23(68):17384-17392. doi: 10.1002/chem.201704406. Epub 2017 Nov 14.
9
Redox reactions between phosphines (R3P; R = nBu, Ph) or carbene (iPr2IM) and chalcogen tetrahalides ChX4 (iPr2IM = 2,5-diisopropylimidazole-2-ylidene; Ch = Se, Te; X = Cl, Br).膦（R3P；R = 正丁基、苯基）或卡宾（异丙基二咪唑（iPr2IM））与硫族四卤化物ChX4（iPr2IM = 2,5 - 二异丙基咪唑 - 2 - 亚基；Ch = 硒、碲；X = 氯、溴）之间的氧化还原反应。
Inorg Chem. 2007 Oct 15;46(21):8594-602. doi: 10.1021/ic700627f. Epub 2007 Sep 12.
10
The spectroscopic (FT-IR, FT-Raman, dispersive Raman and NMR) study of ethyl-6-chloronicotinate molecule by combined density functional theory.结合密度泛函理论对6-氯烟酸乙酯分子进行光谱学（傅里叶变换红外光谱、傅里叶变换拉曼光谱、色散拉曼光谱和核磁共振光谱）研究。
Spectrochim Acta A Mol Biomol Spectrosc. 2016 Jan 15;153:754-70. doi: 10.1016/j.saa.2015.09.007. Epub 2015 Sep 21.

引用本文的文献

1
Synergistic Interplay between Intermolecular Halogen and Chalcogen Bonds in the Dihalogen Adducts of 2,5-Bis(pyridine-2-yl)tellurophene: Reactivity Insights and Structural Trends.2,5-双（吡啶-2-基）碲吩二卤化物中分子间卤素键和硫族元素键的协同相互作用：反应活性见解与结构趋势
Inorg Chem. 2025 Jun 9;64(22):10972-10988. doi: 10.1021/acs.inorgchem.5c01084. Epub 2025 May 29.
2
Formation of extended polyiodides at large cation templates.在大阳离子模板上形成扩展多碘化物。
Acta Crystallogr C Struct Chem. 2024 Jul 1;80(Pt 7):311-318. doi: 10.1107/S2053229624004194. Epub 2024 May 13.

本文引用的文献

1
Reactions of Organoselenenyl Iodides with Thiouracil Drugs: An Enzyme Mimetic Study on the Inhibition of Iodothyronine Deiodinase.有机硒鎓碘化物与硫脲类药物的反应：对碘甲状腺原氨酸脱碘酶抑制作用的模拟酶研究
Angew Chem Int Ed Engl. 2001 Jul 2;40(13):2486-2489. doi: 10.1002/1521-3773(20010702)40:13<2486::AID-ANIE2486>3.0.CO;2-N.
2
1,2-Bis(3-methyl-imidazolin-2-ylium iodobromoselenanide)ethane: Oxidative Addition of IBr at the Se Atom of a >C=Se Group.1,2-双（3-甲基-咪唑啉-2-鎓碘溴硒化物）乙烷：在>C=Se基团的硒原子处IBr的氧化加成反应
Angew Chem Int Ed Engl. 2001 Nov 19;40(22):4229-4232. doi: 10.1002/1521-3773(20011119)40:22<4229::AID-ANIE4229>3.0.CO;2-G.
3
Structural characterization of selenium and selenium-diiodine analogues of the antithyroid drug 6-n-propyl-2-thiouracil and its alkyl derivatives.
抗甲状腺药物6-正丙基-2-硫脲嘧啶及其烷基衍生物的硒和硒-二碘类似物的结构表征
Acta Crystallogr B. 2006 Aug;62(Pt 4):580-91. doi: 10.1107/S0108768106011426. Epub 2006 Jul 12.
4
Synthesis, structural characterization, and computational studies of novel diiodine adducts with the heterocyclic thioamides N-methylbenzothiazole-2-thione and benzimidazole-2-thione: implications with the mechanism of action of antithyroid drugs.新型二碘加合物与杂环硫代酰胺N-甲基苯并噻唑-2-硫酮和苯并咪唑-2-硫酮的合成、结构表征及计算研究：与抗甲状腺药物作用机制的关联
Inorg Chem. 2005 Nov 14;44(23):8617-27. doi: 10.1021/ic0484396.
5
DFT calculations, structural and spectroscopic studies on the products formed between IBr and N,N'-dimethylbenzoimidazole-2(3H)-thione and -2(3H)-selone.关于IBr与N,N'-二甲基苯并咪唑-2(3H)-硫酮和-2(3H)-硒酮反应生成产物的密度泛函理论（DFT）计算、结构和光谱研究。
Dalton Trans. 2005 Jul 7(13):2252-8. doi: 10.1039/b503883a. Epub 2005 May 31.
6
Pd-Dissolution through a mild and effective one-step reaction and its application for Pd-recovery from spent catalytic converters.通过温和有效的一步反应实现钯的溶解及其在从废催化转化器中回收钯的应用。
Chem Commun (Camb). 2005 Feb 28(8):1040-2. doi: 10.1039/b415799k. Epub 2005 Jan 10.
7
First example of an infinite polybromide 2D-network.无限多溴化物二维网络的首个实例。
Chem Commun (Camb). 2003 Sep 7(17):2226-7. doi: 10.1039/b306841b.
8
Halogen-bond geometry: a crystallographic database investigation of dihalogen complexes.卤素键几何结构：二卤化物配合物的晶体学数据库研究
Acta Crystallogr B. 2003 Aug;59(Pt 4):512-26. doi: 10.1107/s0108768103011510. Epub 2003 Jul 25.
9
Construction of the first cross-linked double helical polyiodide.首个交联双螺旋聚碘化物的构建。
Chem Commun (Camb). 2003 Jul 7(13):1488-9. doi: 10.1039/b303289b.
10
Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex.一种新型二茂铁基 - 二碘电荷转移配合物的结构和磁性性质
Inorg Chem. 2003 Jun 30;42(13):3975-7. doi: 10.1021/ic034092f.