Yang Hyeyeon, Hong Young-Taek, Kim Sunggak
Center for Molecular Design & Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea.
Org Lett. 2007 Jun 7;9(12):2281-4. doi: 10.1021/ol070548b. Epub 2007 May 11.
The C2-symmetric bis(oxazoline) copper(II) complex proves to be an excellent catalyst in the Friedel-Crafts alkylation of indoles with alpha'-phosphoric enones. The enantioselectivities of this reaction are obtained in up to 98% ee.
C2对称双（恶唑啉）铜（II）配合物被证明是吲哚与α'-磷酸烯酮进行傅克烷基化反应的优良催化剂。该反应的对映选择性高达98%ee。
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