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开罗地区尼罗河沉积物和鱼类中的多氯联苯、多氯二苯并对二噁英和多氯二苯并呋喃残留量

Polychlorinated biphenyl, polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran residues in sediments and fish of the River Nile in the Cairo region.

作者信息

El-Kady Ahmed A, Abdel-Wahhab Mosaad A, Henkelmann Bernhard, Belal Mohamed H, Morsi M Khairy S, Galal Samy M, Schramm Karl-Werner

机构信息

Food Toxicology & Contaminants, National Research Center, Dokki, Cairo, Egypt.

出版信息

Chemosphere. 2007 Aug;68(9):1660-8. doi: 10.1016/j.chemosphere.2007.03.066. Epub 2007 May 24.

Abstract

The levels of organohalogenated contaminants, i.e. PCBs, PCDDs and PCDFs were determined in sediment and fish samples collected from different locations in the River Nile, Egypt. Thirty-six sediment and eighteen fish samples were carried out during a period of 12 months from February 2003 to February 2004. Determination of PCBs and dioxins was carried out using a high resolution GC mass spectrometer. The results indicated that the PCB and PCDD/F mean concentrations in sediment samples ranged from 1461 to 2244 and from 240 to 775pgg(-1) dry wt basis, respectively. The mean concentration of PCBs and PCDD/Fs in fish samples were found to be in the range from 695 to 853pgg(-1) fresh wt for PCB congeners and from 27.7 to 121pgg(-1) lipid for total PCDD/Fs. Moreover, the concentrations of both PCBs and PCDD/Fs were found to be different at different locations along the River Nile. It could be concluded that the contamination of the River Nile is within the permissible limits set by the FDA and the Egyptian Standards for fish and shellfish.

摘要

对从埃及尼罗河不同地点采集的沉积物和鱼类样本中的有机卤化物污染物(即多氯联苯、多氯二苯并二恶英和多氯二苯并呋喃)水平进行了测定。在2003年2月至2004年2月的12个月期间,采集了36个沉积物样本和18个鱼类样本。使用高分辨率气相色谱 - 质谱仪对多氯联苯和二恶英进行测定。结果表明,沉积物样本中多氯联苯和多氯二苯并二恶英/多氯二苯并呋喃的平均浓度分别为1461至2244以及240至775皮克/克(干重)。鱼类样本中多氯联苯同系物的平均浓度在695至853皮克/克(鲜重)范围内,总多氯二苯并二恶英/多氯二苯并呋喃的平均浓度在27.7至121皮克/克(脂质)范围内。此外,尼罗河沿线不同地点的多氯联苯和多氯二苯并二恶英/多氯二苯并呋喃浓度均有所不同。可以得出结论,尼罗河的污染程度在食品药品监督管理局(FDA)和埃及鱼类及贝类标准规定的允许限度内。

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