一种用于一系列芳基硼酸与芳基氯化物进行微波加速交叉偶联的便捷催化剂体系。
A convenient catalyst system for microwave accelerated cross-coupling of a range of aryl boronic acids with aryl chlorides.
作者信息
Clarke Matthew L, France Marcia B, Fuentes Jose A, Milton Edward J, Roff Geoffrey J
机构信息
School of Chemistry, University of St Andrews, EaStCHEM, St Andrews, Fife, UK.
出版信息
Beilstein J Org Chem. 2007 May 30;3:18. doi: 10.1186/1860-5397-3-18.
Abstract
A convenient microwave accelerated cross-coupling procedure between aryl chlorides with a range of boronic acids has been developed. An explanation for the low reactivity of highly fluorinated boronic acids in Suzuki coupling is provided.
摘要
已开发出一种方便的微波加速的芳基氯与一系列硼酸之间的交叉偶联方法。对高度氟化硼酸在铃木偶联中低反应性给出了解释。
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