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瓶装水中的铅:来自玻璃的污染及与原始地下水的比较

Lead in bottled waters: contamination from glass and comparison with pristine groundwater.

作者信息

Shotyk William, Krachler Michael

机构信息

Institute of Environmental Geochemistry, University of Heidelberg, INF 236, D-69120 Heidelberg, Germany.

出版信息

Environ Sci Technol. 2007 May 15;41(10):3508-13. doi: 10.1021/es062964h.

Abstract

Using clean lab methods and protocols developed for measuring lead (Pb) in polar snow and ice, we report the abundance of Pb in 125 brands of bottled water from 28 countries. Comparison of six samples of each of three brands of water available in both glass and polyethyelene terephthalate (PET(E)) showed that the waters bottled in glass contained approximately 57, 30, and 26 times more Pb due to leaching from the containers. Excluding the bottled waters in glass, the median Pb concentration in all bottled waters was found to be 8.5 ng/L (n=185), with a range from <1 to 761 ng/L Pb. Our study includes 25 brands of bottled water from Canada, and the median Pb concentration in these samples was 15.9 ng/L (n=25), with a range from 2.1 to 268 ng/L. For comparison with the bottled waters, pristine groundwater from six artesian flows in southern Ontario, Canada, where some of the bottled waters originate, yielded a median concentration of 5.1 ng/L Pb (n=18). The median Pb concentrations reported here for bottled waters from Canada are 32-588 times less than those presented in recently published studies. In fact, all of the waters tested were well below the maximum allowable concentration established by the EU, Health Canada, and the WHO for Pb in drinking water (10 microg/L).

摘要

我们采用为测量极地冰雪中的铅(Pb)而开发的清洁实验室方法和规程,报告了来自28个国家的125个品牌瓶装水中铅的含量。对三种品牌、玻璃瓶装和聚对苯二甲酸乙二酯(PET(E))瓶装的各六个水样进行比较,结果显示,玻璃瓶装水中的铅含量因容器溶出而分别高出约57倍、30倍和26倍。排除玻璃瓶装水后,所有瓶装水的铅浓度中位数为8.5纳克/升(n = 185),铅含量范围为<1至761纳克/升。我们的研究涵盖了来自加拿大的25个品牌瓶装水,这些样品中的铅浓度中位数为15.9纳克/升(n = 25),范围为2.1至268纳克/升。为了与瓶装水作比较,我们检测了加拿大安大略省南部部分瓶装水的水源地——六个自流井的原生地下水,其铅浓度中位数为5.1纳克/升(n = 18)。这里报告的加拿大瓶装水的铅浓度中位数比最近发表的研究结果低32至588倍。事实上,所有检测的水样均远低于欧盟、加拿大卫生部和世界卫生组织规定的饮用水中铅的最大允许浓度(10微克/升)。

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