Pifferi Antonio, Torricelli Alessandro, Taroni Paola, Comelli Daniela, Bassi Andrea, Cubeddu Rinaldo
ULTRAS-CNR-INFM and IFN-CNR, Politecnico di Milano, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy.
Rev Sci Instrum. 2007 May;78(5):053103. doi: 10.1063/1.2735567.
We describe a system for absorption and scattering spectroscopy of diffusive media based on time-resolved reflectance and transmittance measurements. The system is operated with mode-locked lasers tunable in the 550-1050 nm spectral range and on a detection chain based on time-correlated single-photon counting. All measurement procedures such as laser tuning and optimization, signal conditioning, data acquisition, and analysis are completely automated, permitting spectral measurements over the whole range in a few minutes. The criticalities of the system are discussed together with the strategies to compensate them. The Medphot protocol devised for the characterization of photon migration instruments was applied to assess the system performances in terms of accuracy, linearity, noise, stability, and reproducibility. Finally, an example of application of the instrument to the spectroscopy of powders is presented.
我们描述了一种基于时间分辨反射率和透射率测量的漫射介质吸收和散射光谱系统。该系统由锁模激光器驱动,其波长可在550 - 1050 nm光谱范围内调谐,并基于时间相关单光子计数的检测链进行操作。所有测量程序,如激光调谐与优化、信号调节、数据采集和分析均完全自动化,能够在几分钟内完成整个范围内的光谱测量。文中讨论了该系统的关键问题以及补偿这些问题的策略。为表征光子迁移仪器而设计的Medphot协议被用于评估该系统在准确性、线性度、噪声、稳定性和可重复性方面的性能。最后,给出了该仪器在粉末光谱分析中的一个应用实例。