Blade L M, Yencken M Story, Wallace M E, Catalano J D, Khan A, Topmiller J L, Shulman S A, Martinez A, Crouch K G, Bennett J S
National Institute for Occupational Safety and Health. Cincinnati, OH 45226, USA. LMB1@cdc,gov
J Occup Environ Hyg. 2007 Aug;4(8):596-618. doi: 10.1080/15459620701463183.
The National Institute for Occupational Safety and Health (NIOSH) conducted 21 field surveys in selected industries to characterize workers' exposures to hexavalent chromium-containing airborne particulate and to evaluate existing technologies for controlling these exposures. Hexavalent chromium Cr(VI) is a respiratory irritant and chronic inhalation may cause lung cancer. Primary evaluation methods included collection of full work shift, personal breathing-zone (PBZ) air samples for Cr(VI), measurement of ventilation system parameters, and documentation of processes and work practices. This study emphasized evaluation of engineering exposure control measures, so PBZ exposures were measured on the outside of personal protective equipment, for example, respirators. Field surveys were conducted in two chromium electroplating facilities, including one where full-shift PBZ exposures to Cr(VI) ranged from 3.0 to 16 times the 1 micro g/m(3)NIOSH recommended exposure limit (REL) despite several engineering controls on the plating tanks. At a painting and coating facility that used Cr(VI)-containing products, full-shift exposures of painters and helpers (2.4 to 55 micro g/m(3)) exceeded the REL, but LEV effectiveness was limited. Other operations evaluated included welding in construction; metal cutting operations on chromium-containing materials in ship breaking; chromate-paint removal with abrasive blasting; atomized alloy-spray coating; foundry operations; printing; and the manufacture of refractory brick, colored glass, prefabricated concrete products, and treated wood products. NIOSH researchers concluded that, in many of the evaluated processes, Cr(VI) exposures at or below the current NIOSH REL are achievable. However, for some processes, it is unclear whether controlling exposures to this range is consistently achievable without respirator use. Some operations involving the application of coatings and finishes may be among those most difficult to control to this range. Most operations judged to be moderately difficult to control to this range involve joining and cutting metals with relatively high chromium content. Nonetheless, exposures in a wide variety of other processes were judged more easily controllable to the current REL or below, or were found to be minimal, including some operations meeting the general descriptions named above but with different specific operating parameters producing lower Cr(VI) exposures.
美国国家职业安全与健康研究所(NIOSH)在选定行业开展了21项实地调查,以确定工人接触含六价铬空气颗粒物的情况,并评估控制这些接触的现有技术。六价铬(Cr(VI))是一种呼吸道刺激物,长期吸入可能导致肺癌。主要评估方法包括采集整个工作班次个人呼吸区(PBZ)的Cr(VI)空气样本、测量通风系统参数以及记录工艺流程和工作实践。本研究重点评估工程接触控制措施,因此在个人防护设备(如呼吸器)外部测量PBZ接触情况。在两家镀铬工厂进行了实地调查,其中一家工厂尽管对镀槽采取了多项工程控制措施,但整个班次PBZ接触Cr(VI)的量仍为美国国家职业安全与健康研究所(NIOSH)推荐接触限值(REL)1微克/立方米的3.0至16倍。在一家使用含Cr(VI)产品的油漆和涂料工厂,油漆工和助手的整个班次接触量(2.至55微克/立方米)超过了REL,但局部排气通风(LEV)效果有限。评估的其他作业包括建筑施工中的焊接;拆船时对含铬材料进行金属切割作业;用喷砂法去除铬酸盐漆;雾化合金喷涂;铸造作业;印刷;以及耐火砖、彩色玻璃、预制混凝土产品和经处理木制品的制造。NIOSH的研究人员得出结论,在许多评估的工艺中,可以实现Cr(VI)接触量达到或低于当前NIOSH的REL。然而,对于某些工艺,不清楚在不使用呼吸器的情况下是否始终能够将接触量控制在这个范围内。一些涉及涂料和饰面应用的作业可能是最难控制到这个范围内的作业之一。大多数被认为难以控制到这个范围内的作业涉及连接和切割含铬量相对较高的金属。尽管如此,各种其他工艺中的接触量被判定更容易控制到当前REL或更低水平,或者被发现接触量极小,包括一些符合上述一般描述但具体操作参数不同从而产生较低Cr(VI)接触量的作业。