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在亚稳磷酸钙溶液中通过电化学沉积在钛基底上形成磷灰石。

Apatite formation on titanium substrates by electrochemical deposition in metastable calcium phosphate solution.

作者信息

Kawashita Masakazu, Itoh Satomi, Miyamoto Kazunori, Takaoka Gikan H

机构信息

Photonics and Electronics Science and Engineering Center, Graduate School of Engineering, Kyoto University, Nisikyo-ku, Kyoto 615-8510, Japan.

出版信息

J Mater Sci Mater Med. 2008 Jan;19(1):137-42. doi: 10.1007/s10856-007-3127-1. Epub 2007 Jun 21.

Abstract

An apatite layer was successfully formed on titanium substrates by electrochemical deposition in a metastable calcium phosphate solution, which had 1.5 times the ion concentrations of a normal simulated body fluid, but did not contain MgCl(2).6H(2)O, at 41 degrees C for 40 or 60 min at 13 mA. The current did not produce large effects on the crystalline size of the apatite, but the thickness of the apatite layer could be controlled by deposition conditions such as electrolyte temperature, current and deposition time. It is expected that the present electrochemical deposition will be useful to rapidly coat apatite on metallic materials.

摘要

在41℃下,以13 mA的电流在亚稳态磷酸钙溶液中通过电化学沉积成功地在钛基底上形成了磷灰石层。该亚稳态磷酸钙溶液的离子浓度是正常模拟体液的1.5倍,但不含MgCl₂·6H₂O,沉积时间为40或60分钟。电流对磷灰石的晶体尺寸没有产生太大影响,但磷灰石层的厚度可以通过诸如电解液温度、电流和沉积时间等沉积条件来控制。预计目前的电化学沉积将有助于在金属材料上快速涂覆磷灰石。

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