三齿的2,6-双（1,2,3-三唑-4-基）吡啶能形成稳定的配位化合物吗？
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
作者信息
Li Yongjun, Huffman John C, Flood Amar H
机构信息
Chemistry Department, Indiana University, 800 East Kirkwood Avenue, Bloomington, IN, USA.
出版信息
Chem Commun (Camb). 2007 Jul 14(26):2692-4. doi: 10.1039/b703301j. Epub 2007 Apr 23.
DOI:10.1039/b703301j
PMID:17594022
Abstract
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.
摘要
在三齿配体中使用的1,2,3 - 三唑基序的首批结构表征实例显示出增强的空间自由度，并且在电生成的Fe(III)状态下对可逆水合具有易接受性。
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