N-（1H）-四唑亚砜亚胺的合成
Synthesis of N-(1H)-tetrazole sulfoximines.
作者信息
Mancheño Olga García, Bolm Carsten
机构信息
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany.
出版信息
Org Lett. 2007 Jul 19;9(15):2951-4. doi: 10.1021/ol071302+. Epub 2007 Jun 27.
PMID:17595098
Abstract
N-(1H)-Tetrazole sulfoximines are readily available by addition of sodium azide to the corresponding N-cyano derivatives in the presence of ZnBr2. The use of these N-(1H)-tetrazoles as intermediates in the synthesis of other N-heterocyclic sulfoximines is demonstrated.
摘要
通过在溴化锌存在下将叠氮化钠添加到相应的N-氰基衍生物中，可以很容易地得到N-（1H）-四唑亚砜亚胺。本文展示了这些N-（1H）-四唑作为中间体用于合成其他N-杂环亚砜亚胺的用途。
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