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具有可调孔径的等规同手性多孔金属有机结构

Isoreticular homochiral porous metal-organic structures with tunable pore sizes.

作者信息

Dybtsev Danil N, Yutkin Maxim P, Peresypkina Eugenia V, Virovets Alexander V, Serre Christian, Férey Gérard, Fedin Vladimir P

机构信息

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 3, Novosibirsk 630090, Russia.

出版信息

Inorg Chem. 2007 Aug 20;46(17):6843-5. doi: 10.1021/ic7009226. Epub 2007 Jul 24.

DOI:10.1021/ic7009226
PMID:17645331
Abstract

Chiral-layered building motifs of zinc(II) camphorate are linked through linear N-donor ligands, forming series of three-dimensional isoreticular porous homochiral frameworks. The lengths of these linear ligands control the pore sizes and free accessible volumes of the homochiral metal-organic structures.

摘要

樟脑酸锌(II)的手性层状建筑单元通过线性氮供体配体相连,形成一系列三维同网多孔同手性框架。这些线性配体的长度控制着同手性金属有机结构的孔径和自由可及体积。

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