Zhang Jian, Wu Tao, Feng Pingyun, Bu Xianhui
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840.
Chem Mater. 2008;20(17):5457-5459. doi: 10.1021/cm801385m.
Three-dimensional assembly of enantiopure D-camphoric acid and in situ synthesized tetradentate 1,2,4,5-tetra(4-pyridyl)benzene (TPB) ligand with tetrahedral Zn(2+) leads to a new homochiral four-connected luminescent material from which the novel TPB ligand can be isolated in the hydrated crystalline form.
对映体纯的D-樟脑酸与原位合成的四齿1,2,4,5-四（4-吡啶基）苯（TPB）配体与四面体Zn(2+)进行三维组装，得到一种新的手性四连接发光材料，从中可以分离出呈水合晶体形式的新型TPB配体。
