Chen Shumei, Zhang Jian, Bu Xianhui
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, California 90840, USA.
Inorg Chem. 2008 Jul 7;47(13):5567-9. doi: 10.1021/ic8007798. Epub 2008 Jun 7.
A new organically templated homochiral material (EMIm)[Co 2( d-cam) 2(ac)] ( 1; d-H 2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid.
一种新型的有机模板手性纯物质(EMIm)[Co₂(d-cam)₂(ac)]（1；d-H₂cam = d-樟脑酸；ac = 乙酸根；EMIm = 1-乙基-3-甲基咪唑鎓）已通过离子热合成法制备，其具有一种不同寻常的乙酸根柱撑钴樟脑酸盐结构，该结构包裹着离子液体的阳离子成分。
